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羟乙基甲基纤维素对水泥水化产物Ca(OH)2形貌特征的影响
Effect of Hydroxyethyl Methyl Cellulose on the Morphology Characteristics of Ca(OH)2 in Portland Cement Paste
投稿时间:2016-09-23  修订日期:2016-11-04
DOI:103969/j.issn.1007 9629201704001
中文关键词:  水泥浆体  羟乙基甲基纤维素  氢氧化钙  形貌特征  聚合物膜
英文关键词:cement paste  hydroxyethyl methyl cellulose  calcium hydroxide  morphology characteristics  polymer film
基金项目:“十三五”国家重点研发计划项目(2016YFC0700905);国家自然科学基金资助项目(51102182);中德科学基金研究交流中心国际科研合作项目(GZ1290);高性能土木工程材料国家重点实验室开放基金项目(2014CEM006);同济大学大型仪器测试开放基金(0002016051)
              
作者单位
张国防
ZHANG Guofang
同济大学先进土木工程材料教育部重点实验室,上海201804
Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, Tongji University, Shanghai 201804, China
和瑞
HE Rui
同济大学先进土木工程材料教育部重点实验室,上海201804
Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, Tongji University, Shanghai 201804, China
赵国荣
ZHAO Guorong
同济大学先进土木工程材料教育部重点实验室,上海201804
Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, Tongji University, Shanghai 201804, China
王亚文
WANG Yawen
同济大学先进土木工程材料教育部重点实验室,上海201804
Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, Tongji University, Shanghai 201804, China
王培铭
WANG Peiming
同济大学先进土木工程材料教育部重点实验室,上海201804
Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, Tongji University, Shanghai 201804, China
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中文摘要:
      利用场发射扫描电子显微镜(ESEM)研究了羟乙基甲基纤维素(HEMC)对水泥水化产物Ca(OH)2形貌特征的影响以及HEMC的成膜特性.结果表明:羟乙基甲基纤维素会对水泥水化产物Ca(OH)2的形貌特征和生长取向性产生显著影响,并导致气孔中生成较多的Ca(OH)2,使得水泥浆体及其气孔中Ca(OH)2晶体的生长呈现出多向性,其形貌特征多呈X形状或花瓣状,这种影响在水化早期尤为显著;羟乙基甲基纤维素能在水泥浆体中形成细小的线状聚合物膜,也有少量的连续聚合物膜,并搭接在Ca(OH)2晶体表面及其层隙之间,起到了一定的桥接作用,改善了Ca(OH)2晶体之间的界面特性.
英文摘要:
      The effect of hydroxyethyl methyl cellulose(HEMC) on the morphology of calcium hydroxide(Ca(OH)2) and the formation of polymer films in cement paste at different curing ages were studied by using environmental scanning electron microscopy(ESEM). The results show that HEMC dramatically affects the morphology and the oriented growth of Ca(OH)2 in cement paste. HEMC also increases the enrichment of Ca(OH)2 in pores, thus enhances the multidirectional growth of Ca(OH)2 which exhibit X shape or petal like morphologies both in cement paste and in pores, especially at earlier hydration time. Tiny linear polymer films of HEMC are formed in cement paste, bridging the Ca(OH)2 plates and even covering on them, and accordingly to improve the interfacial characteristics of Ca(OH)2 plates.
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