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碳化对钢渣水泥 CaO MgO砂浆强度和微观结构的影响
Effect of Carbonation Curing on Mechanical Strength and Microstructure of Mortars Prepared with Steel Slag Cement MgO CaO Blends
投稿时间:2016-11-14  修订日期:2017-01-16
DOI:103969/j.issn.1007 9629201706005
中文关键词:  钢渣  MgO  碳化  抗压强度  微观结构
英文关键词:steel slag  magnesium oxide  carbonation  compressive strength  microstructure
基金项目:国家自然科学基金资助项目(51461135003, 51502134);江苏省高校自然科学研究项目(14KJB560009)
           
作者单位
张丰
ZHANG Feng
南京水利科学研究院,江苏南京210029
Nanjing Hydraulic Research Institute, Nanjing 210029, China
莫立武
MO Liwu
南京工业大学材料科学与工程学院,江苏南京210009
College of Materials Science and Engineering, Nanjing Tech University, Nanjing 210009, China
邓敏
DENG Min
南京工业大学材料科学与工程学院,江苏南京210009
College of Materials Science and Engineering, Nanjing Tech University, Nanjing 210009, China
蔡跃波
CAI Yuebo
南京水利科学研究院,江苏南京210029
Nanjing Hydraulic Research Institute, Nanjing 210029, China
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中文摘要:
      以钢渣粉为主要胶凝材料,掺入MgO,CaO和水泥等材料制备砂浆试件,经碳化养护后测试其抗压强度及微观结构,并研究碳化后砂浆试件的强度变化机理.结果表明:经碳化处理后,砂浆试件抗压强度显著提高,碳化1d后即提高39~68倍,且砂浆试件碳化时间越长,碳化程度越高,其抗压强度也越高;CaO和MgO的掺入有利于碳化后砂浆强度的提高,当掺入5%(质量分数)CaO和15%(质量分数)MgO时,碳化14d后砂浆试件抗压强度最高,可达716MPa;碳化过程中生成了大量碳化产物——方解石CaCO3(碳酸钙镁CaxMg1-xCO3)和文石CaCO3,碳化产物填充孔隙、改善了颗粒界面结构,使得砂浆试件孔隙率降低,抗压强度得以提高.
英文摘要:
      Steel slag powders were used as the main component of cementitious materials, and MgO, CaO and Portland cement were incorporated to prepare mortar specimens. The mortars were then exposed to CO2 curing to test the compressive strength and microstructure and investigate the mechanism of improving strength of carbonation curing. The results show that the compressive strengths of mortars increase significantly after the carbonation curing, by 3968 times after only 1d of carbonation. Prolonging the carbonation curing time facilitate the carbonation reaction, and hence increases the degree of carbonation and enhances the strength gain of mortars. The incorporation of CaO and MgO components increases the compressive strengths of mortars, and the highest compressive strength can reach 716MPa after 14d of carbonation, when 5%(by mass) CaO and 15%(by mass) MgO are incorporated. The treatment of CO2 curing decreases the total pore volume of mortar specimens due to the microstructure densification as a result of the formation of calcite CaCO3(calcium magnesium CaxMg1-xCO3) and aragonite CaCO3.
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