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核酸阻锈剂在模拟混凝土孔溶液中对钢筋的阻锈作用
Corrosion Inhibition Effect of Nucleic Acid Corrosion Inhibitor on Rebar in Simulated Concrete Pore Solutions
投稿时间:2016-11-24  修订日期:2017-01-01
DOI:103969/j.issn.1007 9629201706007
中文关键词:  核酸  阻锈剂  模拟混凝土孔溶液  电化学方法  锈蚀
英文关键词:nucleic acid  corrosion inhibitor  simulated concrete pore solution  electrochemical technique  corrosion
基金项目:国家自然科学基金资助项目(51278167);“十三五”国家科技支撑计划项目(2015BAB07B04);中央高校基本科研业务费专项资金资助项目(2016B04514)
                 
作者单位
蒋林华
JIANG Linhua
河海大学力学与材料学院,江苏南京210098
College of Mechanics and Materials, Hohai University, Nanjing 210098, China
姜少博
JIANG Shaobo
河海大学力学与材料学院,江苏南京210098
College of Mechanics and Materials, Hohai University, Nanjing 210098, China
王珠银
WANG Zhuyin
河海大学力学与材料学院,江苏南京210098
College of Mechanics and Materials, Hohai University, Nanjing 210098, China
金鸣
JIN Ming
河海大学力学与材料学院,江苏南京210098
College of Mechanics and Materials, Hohai University, Nanjing 210098, China
白舒雅
BAI Shuya
河海大学力学与材料学院,江苏南京210098
College of Mechanics and Materials, Hohai University, Nanjing 210098, China
宋诗琦
SONG Shiqi
河海大学力学与材料学院,江苏南京210098
College of Mechanics and Materials, Hohai University, Nanjing 210098, China
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中文摘要:
      将一种具有20~80个碱基长度的核酸引物混合溶液溶解在缓冲液中作为核酸阻锈剂.采用电化学阻抗谱、动电位极化方法研究了核酸阻锈剂在不同NaCl浓度的模拟混凝土孔溶液中对钢筋的阻锈作用及其机理,并提出了核酸阻锈剂的最佳掺量.利用X射线光电子能谱(XPS)分析了在核酸阻锈剂作用下钢筋电极表面吸附膜的组成结构.结果表明:核酸阻锈剂能显著提高钢筋的耐蚀性,核酸阻锈剂的最佳掺量为模拟混凝土孔溶液总质量的4%.核酸与钢筋具有良好的协同效应,吸附在钢筋表面的核酸能够形成一层致密的薄膜,可有效阻止外来离子的侵蚀,使钢筋具有优越的耐蚀性.
英文摘要:
      A mixed solution that had a length of 20 to 80 bases of each primer in nucleic acid buffer was used as nucleic acid corrosion inhibitor. The corrosion inhibition effect and mechanism of nucleic acid corrosion inhibitor on rebar in simulated concrete pore(SCP) solutions with different concentrations of NaCl were investigated by electrochemical impedance spectroscopy and potentiodynamic polarization.The best dosage of the nucleic acid corrosion inhibitor was also investigated. The chemical composition of the adsorption films on the rebar surface was investigated using X ray photoelectron spectroscopy(XPS). It is found that the nucleic acid has an excellent corrosion inhibition effect, and the added amount of 4% nucleic acid by simulated concrete pore solutions mass is the best dosage. There is an excellent synergistic effect between nucleic acid and rebar. The nucleic acid is greatly adhered to the rebar surface and a dense film is formed which can restrict the corrosion attack and provide superior corrosion inhibition.
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